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155. Studies of trifluoroacetic acid. Part III. The use of trifluoroacetic anhydride in the synthesis of aromatic ketones and sulphones

✍ Scribed by Bourne, E. J. ;Stacey, M. ;Tatlow, J. C. ;Tedder, J. M.

Book ID: 115509940
Publisher: The Royal Society of Chemistry
Year: 1951
Weight: 274 KB
Category: Article
ISSN: 0368-1769
DOI: 10.1039/jr9510000718

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The stable and non-hygroscopic aluminum dodecatungstophosphate (AlPW 12 O 40 ), was found to be an effective catalyst (3 mol%) for the solvent-free Friedel-Crafts acylation of aromatic compounds with carboxylic acids in the presence of trifluoroacetic anhydride under mild reaction conditions.

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