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15 N Solid-State NMR Characterization of Ammonia Adsorption Environments in 3A Zeolite Molecular Sieves

✍ Scribed by Holland, G. P.; Cherry, B. R.; Alam, T. M.


Book ID
126908734
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
165 KB
Volume
108
Category
Article
ISSN
0022-3654

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Observation and characterization by 15N
✍ Ferdinand MΓ€nnle; Iwona Wawer; Hans-Heinrich Limbach πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 378 KB

Using dynamic 15N CPMAS NMR spectroscopy a novel double proton transfer was detected in the cyclic hydrogen bonded dimers of polycrystalline tSN,ZSN'-di-(4-bromophenyl)-formamidine. Rate constants of this process, which is degenerate within the margin of error, were obtained by lineshape (kl2 = 10 6