NH2(CH&CH3 and (for Pt) C2H4. For both metals, the NMR. parameters depend on the trans-influence of the ligand L. The values 1J(195Pt, 15N) vary from 138 to 336 Hz and can be shown to correlate with the values 1J(195Pt, 31P) in the complexes trans-[PtCl,(PBu!j)L]. There is a linear relation between
โฆ LIBER โฆ
15 N AND 31 P NMR STUDIES OF CYANO(TRIALKYL/TRIARYL)PHOSPHINE GOLD(I) COMPLEXES
โ Scribed by Akhtar, M. Naseem; Gazi, Ibrahim H.; Isab, Anvarhusein A.; Al-Arfaj, Abdul Rahman; Wazeer, Mohammed I.M.; Hussain, M. Sakhawat
- Book ID
- 120416871
- Publisher
- Taylor and Francis Group
- Year
- 1995
- Tongue
- English
- Weight
- 437 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0095-8972
No coin nor oath required. For personal study only.
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I9'Pt-, 31Pand "N-NMR. data are presented for [PtCl, (t-Bu15N=CH-CH=15N (t-Bu)) (q2-styrene)] (l), truns-[(PtC12 (PBu3)}, (~-BU'~N=CH-C'H=I~N (2-Bu))] (2), trans-[PtCI, (~-Bu"N=CH-CH='~N (t-Bu)) (PBu,)] (3) and various complexes of the type truns-[PtCl, (N-ligand) (PBu,)]. In solution the gross stru