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14N Hyperfine Structure in the Pure Rotational Spectrum of24Mg14N12C

✍ Scribed by Kaley A. Walker; Michael C.L. Gerry

Publisher: Elsevier Science
Year: 1998
Tongue: English
Weight: 149 KB
Volume: 189
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.1997.7515

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✦ Synopsis

The pure rotational spectrum of 24 Mg 14 N 12 C, between 11.9 and 23.9 GHz, has been measured using a pulsed jet Fourier transform microwave spectrometer. The hyperfine structure due to the 14 N nucleus has been measured, and the nuclear quadrupole coupling, Fermi contact, and dipole-dipole interaction constants have been determined. The ionic character of the metal-isocyanide bond has been investigated through the nuclear quadrupole and magnetic hyperfine parameters.

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