14N and 1H ENDOR and TRIPLE resonance on azaaromatic radicals produced by sodium reduction in liquid ammonia
✍ Scribed by W Lubitz; T Nyrönen
- Publisher
- Elsevier Science
- Year
- 1980
- Weight
- 774 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0022-2364
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## Abstract The relative signs and absolute values of the hyperfine coupling constants of different methoxy‐1,4‐benzoquinones were measured by ESR, ENDOR and TRIPLE resonance spectroscopy. Reactions of 1,4‐benzoquinone and 1,4‐hydroquinone with methanol took place in alkaline methanol, giving rise
A variety of isotopically labelled and/or substituted flavins have been converted into their corresponding radical states. Cation and neutral radicals were generated chemically and anion radicals were obtained electrochemically. By performing ENDOR and TRIPLE resonance experiments, complete sets of