1,4,7-Trithiacyclononane, a novel tridentate thioether ligand, and the structure of its nickel(II), cobalt(II), and copper(II) complexes
β Scribed by Setzer, William N.; Ogle, Craig A.; Wilson, George S.; Glass, Richard S.
- Book ID
- 121416071
- Publisher
- American Chemical Society
- Year
- 1983
- Tongue
- English
- Weight
- 774 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0020-1669
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## Abstract Synthesis of four different types of ligands Ar[COC(NOH)R]n (Ar = biphenyl, n = 1, HL1; Ar = biphenyl, n = 2, H2L2; Ar = diphenylmethane, n = 1, HL3; Ar = diphenylmethane, n = 2, H2L4; R = furfurylamine in all ligands) and their dinuclear Co2+, Ni2+, Cu2+, and Zn2+ complexes is reported
ESR and absorption spectra were measured for the square planar cobalt(II), nickel(II) and copper complexes with some I4, 15 and 16membered N4macrocyclic ligands, such as (14-a), H(14-b), H,(14c), HJIS-c) and H,(16-c) (for the abbreviations, see Fig. 2 in the text). On the basis of the ESR spectra of