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1,4-Diazo­niabi­cyclo­[2.2.2]­octane tri­aqua­tri­chloro­nickelate(II) chloride monohydrate

✍ Scribed by Bremner, Colin A. ;Harrison, William T. A.


Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
384 KB
Volume
59
Category
Article
ISSN
1600-5368

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The title compound, C 6 H 14 N 2 2+ Á2NO 3 À , was synthesized under hydrothermal conditions. The asymmetric unit consists of one protonated 1,4-diazabicyclo[2.2.2]octane (DABCO) molecule and two nitrate anions. The structure is stabilized by hydrogen bonding of the nitrate O atoms to the protonated

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The title compound, (C 6 H 14 N 2 )[Co(H 2 O) 6 ](SO 4 ) 2 , consists of hexaaquacobalt(II) cations, 1,4-diazabicyclo[2,2,2]octane cations and sulfate anions, linked by O-HÁ Á ÁO hydrogen bonds. The geometry around the Co 2+ cation is octahedral.