1,4-Bis[chloro(hydroxyimino)methyl]benzene N,N′-dimethylformamide disolvate
✍ Scribed by Liu, Xin-Gang ;Feng, Ya-Qing ;Liu, Dong-Qing ;Zhao, Yao
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 137 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The structure of the centrosymmetric title compound, C 8 H 6 Cl 2 N 2 O 2 Á2C 3 H 7 NO, shows that the hydroximoyl chloride substituent has an essentially planar arrangement and the dihedral angle between this plane and the benzene plane is 18.3 (4) . The hydroximoyl chloride group has a cis configuration. The packing can be described as a polymeric arrangement of molecules linked through O-HÁ Á ÁO hydrogen bonds.
📜 SIMILAR VOLUMES
The title compound, C 10 H 11 Cl 2 NO 2 , consists of a benzene core functionalized by one nitro group, two methyl groups, and two chloromethyl groups. The crystal structure is stabilized by intermolecular C-HÁ Á ÁO non-classical hydrogen bonds and weak C-HÁ Á ÁCl interactions.
Di-l-acetato-bis[l-2-hydroxy-N,N 0 0 0 -bis(2-oxidobenzyl)propane-1,3-diamine]bis(N,N 0 0 0 -dimethylformamide)trinickel(II) N,N 0 0 0 -dimethylformamide disolvate
The title compound, C 42 H 44 N 2 O 8 S 2 , features a molecular thread. The molecules have crystallographic C i symmetry. The crystal packing shows staples stabilized by weak C-HÁ Á ÁO interactions.