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1,4-Bis(arylsulfonyl)-1,2,3,4-tetrahydropyridines in Synthesis: Stereoselective Homo- and Hetero-Diels—Alder Reactions.

✍ Scribed by Jean-Claude Adelbrecht; Donald Craig; Alice J. Fleming; Fionna M. Martin


Publisher
John Wiley and Sons
Year
2006
Weight
34 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis


Pyridine derivatives R 0380 1,4-Bis(arylsulfonyl)-1,2,3,4-tetrahydropyridines in Synthesis: Stereoselective Homo-and Hetero-Diels-Alder Reactions. -Pyridines (III) bearing a 1,3-diene moiety undergo cycloaddition reactions with nitroso species or unsaturated carbonyl compounds to give novel bicyclic compounds in a highly stereoselective manner. -(ADELBRECHT,


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ChemInform Abstract: 1,4-Bis(arylsulfony
✍ D. CRAIG; R. MCCAGUE; G. A. POTTER; M. R. V. WILLIAMS 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 37 KB 👁 1 views

1,4-Bis(arylsulfonyl)-1,2,3,4-tetrahydropyridines in Synthesis. Intramolecular Alkylation Reactions and Stereoselective Synthesis of anti-2,6-Disubstituted Piperidines. -Chiral tetrahydropyridines (I) undergo intramolecular aromatic substitution reactions to give benzofused bicyclic compounds (II)