In the title complex, [Cd(NO 3 ) 2 (C 25 H 19 N 3 O 2 )], the coordination environment around cadmium consists of four O and three N atoms in the form of a distorted pentagonal bipyramid.
1,4-Bis(8-quinolyloxymethyl)benzene
✍ Scribed by Steel, Peter J. ;Al-Mandhary, Muna R. A.
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 123 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 168 K Mean '(C±C) = 0.003 A Ê R factor = 0.041 wR factor = 0.107 Data-to-parameter ratio = 11.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.002 A Ê R factor = 0.042 wR factor = 0.138 Data-to-parameter ratio = 12.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, C 18 H 12 N 2 O 6 , crystallizes with two halfmolecules in the asymmetric unit. All molecules lie on a centre of inversion. The dihedral angles between the central and terminal benzene rings are 74.75 (4) and 85.25 (5) for the two molecules in the asymmetric unit.
In the title compound, C 15 H 11 BrN 2 O 2 S, the torsion angle about the central C-N-S-C bridge is 55. 1 (5) . The dihedral angle between the planes of the nearly planar quinoline group and the bromobenzene ring is 72.0 (1) . No classical hydrogen bonds were found in the crystal structure.
In the crystal structure of the title compound, C 26 H 34 N 2 O 3 S, the quinoline ring system, with methoxy and methyl substituents, is nearly planar. An intramolecular hydrogen bond [N-HÁ Á ÁN = 2.16 (2) A ˚] is observed.