1,4-Bis(2-mercaptobenzothiazolyl)butane
✍ Scribed by Chen, Chunlong ;Su, Chengyong ;Zhang, Huaxin ;Xu, Anwu ;Kang, Beisheng
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 190 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, C 18 H 18 N 4 , lies on an inversion center. The benzimidazolyl moiety is essentially planar. Intermolecular NÐHÁ Á ÁN hydrogen bonds give rise to an in®nite helical chain structure, with the chains stacked by CÐHÁ Á Á% and %Á Á Á% interactions.
The title compound, C 10 H 14 N 2 S 4 , was synthesized by the reaction of the potassium salt of 2-thiothiazole and 1,4dibromobutane. The two 2-thiazolethio groups are related by a center of symmetry. The plane de®ned by the butyl carbon chain is approximately orthogonal to the thiazole plane, with