The title compound, C 12 H 17 N 3 O, was obtained by the direct solvent-free reaction of salicylaldehyde with 1-amino-4methylpiperazine. The piperazine ring adopts a chair conformation. In the crystal structure, strong intramolecular O-HÁ Á ÁN hydrogen bonds, weak intermolecular C-HÁ Á ÁO hydrogen b
1,4-Bis(1-naphthylmethyl)piperazine
✍ Scribed by Kubo, Kanji ;Yamamoto, Emi ;Hayakawa, Akinori ;Sakurai, Tadamitsu ;Mori, Akira
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 218 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The molecule of the title compound, C~26~H~26~N~2~, sits on a center of symmetry such that the two naphthalene ring systems are in an anti conformation with respect to one another across the piperazine ring. An intermolecular π–π interaction between the naphthalene ring systems is observed.
📜 SIMILAR VOLUMES
The title compound, C~8~H~12~Cl~2~N~2~O~2~, contains two half-molecules in the asymmetric unit. The complete molecule is generated by inversion symmetry in both cases.
In the title compound, C 8 H 8 Br 2 , the molecules are located on inversion centres and are connected through weak intermolecular BrÁ Á ÁBr interactions into layers parallel to the (102) plane.
The title compound, C 23 H 26 BrN 5 O 2 , was synthesized by the reaction of 4- [(2,6-dimethylphenyl)aminocarbonylmethyl]piperazine and 3-(3-nitrophenyl)-5-chloromethyl-1,2,4-oxadiazole. There are intramolecular C-HÁ Á ÁN and intermolecular N-HÁ Á ÁO and C-HÁ Á ÁO hydrogen bonds in the crystal struc