1.3λ3-Azaphospholo[1.2-α]pyridine - 1.2.4.λ3-diazaphospholo[1.5-α]pyridine - 1.3λ3-azaarsolo[1.5-α]pyridine - 1.2.4λ3-diazaarsolo[1.5-α]pyridine
✍ Scribed by G Märkl; S Pflaum
- Book ID
- 104233432
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- French
- Weight
- 207 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
The title compounds are prepared by reaction Of 1.3-oxasolo[ 3,2_alpyridinium-and 1.3.4-oxadiaeoloC3.2-alpyridiniumsalts with P(SiMe3)3,resp. As(SiMe3>3. In 2.4.6-Stellung trisubstituierte Pyryliumsalze reagieren sowohl mit
📜 SIMILAR VOLUMES
I ,I ,3,3 -Tetrakis(dimethylamin0) -1 h5,3h5diphosphete, 1, reacts with cyanoformic acid methyl ester to form two isomers of the title compound 2. Properties, NMR, mass, and IR spectra of 2, as well as the molecular and crystal structure of the E isomer of 2, are described and discussed.
The title compounds are described for the first time and are the result of (3+2)-and (4+2)-cycloaddition reactions with phosphaalkenes. tfoer Untersuchungen zu (4+2)-und (3+2)-Cycloadditionen von l-cblorphosphaalkenen la,b mit offenkettigen und cyclischen Dienen Cl.2.31 und mit 1,3-Dipolen (Diazoalk