13C–27Al TRAPDOR and REDOR Experiments for the Detection of 13C–27Al Dipolar Interactions in Solids

✍ Scribed by Leo van Wüllen; Martin Kalwei

• Publisher: Elsevier Science
• Year: 1999
• Tongue: English
• Weight: 132 KB
• Volume: 139
• Category: Article
• ISSN: 1090-7807
• DOI: 10.1006/jmre.1999.1765

✦ Synopsis

We report (13)C-(27)Al double resonance experiments (REDOR and TRAPDOR) on several aluminum organic compounds with the aim of detecting (13)C-(27)Al dipolar couplings and distances in solids. The (13)C and (27)Al pulses are applied to the same probe channel because their resonance frequencies are in close proximity. The different possibilities of controlling the efficiency of the TRAPDOR approach (by varying the (27)Al RF amplitude and the MAS frequency) are investigated. The results indicate that TRAPDOR is superior to REDOR in resolving differences in (13)C-(27)Al distances when choosing the proper experimental conditions. Where known, the crystal structure data are in qualitative agreement with the distance information extracted from our experiments. The experiment should be very valuable in different fields of solid state chemistry, where the interaction of organic and inorganic sample fractions is of fundamental importance.