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13C1H Coupling Constants in Fluoropyridines

✍ Scribed by A. Yu. Denisov; V. I. Mamatyuk; O. P. Shkurko

Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
211 KB
Volume
23
Category
Article
ISSN
0749-1581

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✦ Synopsis

The proton-coupled 13C NMR spectra of 2-, 3-and 4-fluoropyridines were completely analysed and the signs and magnitudes of the 13C-1H coupling constants determined. The root mean square deviations of the observed J(CH) values from those calculated using empirical correlations between the coupling constants in monosubstituted pyridines and benzenes were found to be 0.90 Hz for 'J(CH) and less than 0.26 Hz for the other "J(CH) couplings.

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