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13C,13C coupling constants from a mixture of isotopomers (13C) of substituted aromatic compounds; 1-nitronaphthalenes

✍ Scribed by Poul Erik Hansen; Jean-Pierre Albrand

Publisher: John Wiley and Sons
Year: 1981
Tongue: English
Weight: 198 KB
Volume: 17
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1270170115

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✦ Synopsis

Abstract

^13^C Homonuclear decoupling experiments led to the assignment of the carbon‐carbon coupling constants of ^13^C‐enriched 1‐nitronaphthalene obtained by nitration of [1‐^13^C]naphthalene. The effects of substituents on coupling constants can be explained on the basis of the electronegativity of the first atom of the substituent, and the observed substituent effects are shown to be parallel to previous data for oxygen containing substituents.

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