13C Spin–Lattice Relaxation in Natural Diamond: Zeeman Relaxation in Fields of 500 to 5000 G at 300 K Due to Fixed Paramagnetic Nitrogen Defects

✍ Scribed by Cornelis J. Terblanche; Eduard C. Reynhardt; Sergei A. Rakitianski; Jan A. Van Wyk

• Publisher: Elsevier Science
• Year: 2001
• Tongue: English
• Weight: 290 KB
• Volume: 19
• Category: Article
• ISSN: 0926-2040
• DOI: 10.1006/snmr.2001.0025

✦ Synopsis

13 C Spin-lattice relaxation (SLR) times in the laboratory frame have been measured at room temperature as a function of field in the range of 500 to 5000 G on two natural type Ib and Ia diamonds after dynamic nuclear polarization. Each of the diamonds contains two types of fixed paramagnetic centers with overlapping inhomogeneous electron paramagnetic resonance (EPR) lines. EPR techniques have been employed to identify these defects and to determine their concentrations and relaxation times at X-band. Three different nuclear SLR paths, namely that due to electron SLR and two types of three spin processes, are discussed. The one three-spin process (TSP) (type 1) involves a simultaneous transition of two electron spins belonging to the same hyperfine EPR line and a 13 C spin while the other process (type 2) involves two electron spins belonging to different hyperfine EPR lines and a 13 C spin. It is shown that the thermal contact between the 13 C nuclear Zeeman and electron dipole-dipole interaction reservoirs decreases with an increase in field intensity, thus forming a bottleneck in the 13 C relaxation path due to the type 1 TSP. The contribution of TSP of type 1 dominates that due to electron SLR and the type 2 TSP in relaxing the 13 C nuclei in type Ib diamond from about 1200 to 5000 G, while for type Ia diamond it dominates from 500 up to about 2200 G. In type Ia diamond over the range 2200 to 5000 G it seems that the type 2 TSP, which involves electrons of neighboring P2 hyperfine lines, dominates that of electron spin-lattice and the type 1 TSP. Over the range 500 to about 1200 G, a field-dependent electron SLR mechanism associated with N3 centers appears to dominate the 13 C SLR.