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13C relaxation measurements of molecular motion in micellar solutions

✍ Scribed by R.T. Roberts; C. Chachaty

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
285 KB
Volume
22
Category
Article
ISSN
0009-2614

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✦ Synopsis

Measurements

have been made of the 13C nuclear magnetic resonance longitudinal relaxation time T1 in micellar solutions of sodium kauryl sulphate with different concentration of added sodium chloride. The purpose of the experiment was to see what effect added electrolyte had on the motion of the paraffin chains. It is shown that the methylene group next to the polar head gains more freedom as the electrolyte concentration is increased. The molecular motions inside the micelle do not change.

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