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13C nuclear magnetic resonance of homologous methyl esters of saturated acids and the effect of chemical shift reagents

✍ Scribed by F. E. Barton; D. S. Himmelsbach; D. B. Walters


Book ID
112820521
Publisher
Springer-Verlag
Year
1978
Tongue
English
Weight
309 KB
Volume
55
Category
Article
ISSN
0003-021X

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## Abstract The ^13^C chemical shifts for 1,3‐dithiane and 9 methyl substituted derivatives are reported. Only three of the methyl‐1,3‐dithianes were conformationally anancomeric and hence the conformational equilibria must be taken into account when deriving the values of the different substituent

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The 13C-NMR spectra of 48 cis alkenoic acids and esters (C8-C20), 18 trans alkenoic acids and esters (C9-C18), and 26 polyenoic acids and esters (C18-C22) are reported and interpreted. The characteristic features of such spectra which permit structural assignments to be made are discussed.