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13C NMR Study of the Effect of Coordinating Solvents on Zirconocene-Catalyzed Propene/1-Hexene Copolymerization

✍ Scribed by Fabrizio Forlini; Elisabetta Princi; Incoronata Tritto; Maria Carmela Sacchi; Fabrizio Piemontesi


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
308 KB
Volume
203
Category
Article
ISSN
1022-1352

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The effect of ethylene pressure on the copolymerization of ethylene with 1hexene was studied. The results show an increasing of productivities (g of polymer/ n Zr h) with pressure. This tendency was not observed for the activity (g of polymer/ n Zr h bar) that decreases when pressure is raised. When