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13C NMR spectroscopy of phorbol esters

✍ Scribed by Luc A. C. Pieters; Arnold J. Vlietinck

Publisher: John Wiley and Sons
Year: 1987
Tongue: English
Weight: 253 KB
Volume: 25
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260250420

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✦ Synopsis

Be 1 g i u m biaceae), and of six common acyl substituents of naturally occurring phorbol esters were recorded and the signals assigned. The spectral data for this series of model compounds appeared to be important tools for the identification and the structure elucidation of naturally occurring and semi-synthetic diterpene esters related to phorbol.

seed oil of Croton tiglium L. (Euphorbiaceae).' Nowadays the parent diterpene, phorbol, its naturally occurring esters and its semi-synthetic derivatives are important tools in inflammation and cancer research.' In order to provide additional information for the identification and structure elucidation of such products, it became necessary to obtain the I3C NMR spectral data of a series of model compounds in a systematic manner. Surprisingly, there are few reuorts of the I3C chemical _ _

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