𝔖 Bobbio Scriptorium
✦   LIBER   ✦

13C-NMR. Spectroscopy of Naturally Occurring Substances. XLV. Iboga Alkaloids

✍ Scribed by Ernest Wenkert; David W. Cochran; Hugo E. Gottlieb; Edward W. Hagaman; Raimundo Braz Filho; Francisco José de Abreu Matos; Maria Iracema Lacerda Machado Madruga


Publisher
John Wiley and Sons
Year
1976
Tongue
German
Weight
399 KB
Volume
59
Category
Article
ISSN
0018-019X

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

The carbon shifts of the Iboga‐type alkaloids catharanthine, voacangine, coronaridine, ibogaine, dihydrocatharanthine and epiibogamine were recorded and correlated with the conformation of the natural bases. A ^13^C‐NMR. analysis of heyneanine determined its C(19) configuration and a similar study of epiheyneanine proved its structure.


📜 SIMILAR VOLUMES


13C NMR spectroscopy of natural substanc
✍ A. Arnone; R. Mondelli; J. St Pyrek 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 English ⚖ 322 KB

## Abstract The diterpene trachylobane and a series of derivatives have been completely analysed by FT ^13^C NMR spectroscopy. All ^13^C frequencies for trachylobanol have been unambiguously assigned by experimental techniques, i.e. by proton single‐frequency selective decoupling and shift reagent

The Configuration of Naturally Occurring
✍ Ratan K. Chaudhuri; Fatma Ü. Afifi-Yazar; Otto Sticher 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 German ⚖ 144 KB

## Abstract Evidence is presented which demonstrates that ^13^C‐NMR. spectroscopy can be used with confidence in evaluating the configuration of R^1^R^2^CHOH centers at C(6) and C(8) of iridoid glucosides.

Elemental Quantitation of Natural Organi
✍ P. Conte; A. Piccolo; B. van Lagen; P. Buurman; M.A. Hemminga 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 184 KB

Cross-polarized magic-angle-spinning NMR (CPMAS-NMR) techniques are assumed to be only semi-quantitative in the assessment of carbon distribution in humic substances or natural organic matter, due to a number of interferences such as spinning side bands (SSB) in spectra, paramagnetic species in samp

13C NMR spectroscopy of tri- and tetracy
✍ B. Mikhova; H. Duddeck 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 317 KB 👁 2 views

A comprehensive collection of 13C chemical shifts of 159 tri-and tetracyclic quinolizidine alkaloids (sparteine derivatives) is presented. The data are discussed in terms of substituent e †ects, molecular geometries and protonation e †ects. Some IR, 1H and 15N NMR and MS data are included.