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13C NMR relaxation study of monoaminopyridines in D2O and CDCl3–DMF solutions

✍ Scribed by Flaminia Cesare Marincola; Enzo Cadoni; Gioanna Gelli; Adolfo Lai; Paolo Beltrame

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
34 KB
Volume
37
Category
Article
ISSN
0749-1581

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✦ Synopsis

13

C spin-lattice NMR relaxation rates of pyridine and 4-,3-and 2-aminopyridine were measured in CDCl 3 -DMF and water in the neutral and protonated forms. The relaxation data were analysed in terms of the existence of tight pairs of ions between chloride and protonated pyridine and aminopyridines and/or adducts with the solvent molecules in CDCl 3 -DMF.

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