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13C NMR chemical shifts of some highly-branched acyclic compounds

✍ Scribed by Richard M. Schwarz; Norman Rabjohn

Publisher: John Wiley and Sons
Year: 1980
Tongue: English
Weight: 332 KB
Volume: 13
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1270130103

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✦ Synopsis

Abstract

A study has been made of the ^13^C chemical shifts of a number of acyclic alkanes, alkenes, nitriles and ketones which contain quaternary carbon atoms. Similar data have also been obtained for the series of compounds involved in the synthesis of triisopropylacetic acid. Substituent effects and steric factors in these highly substituted compounds are discussed in relation to the chemical shifts.

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