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13C n.m.r. chemical shifts in aliphatic alcohols and the γ-shift caused by hydroxyl and methyl groups

✍ Scribed by Andrzej Ejchart


Book ID
102525420
Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
334 KB
Volume
9
Category
Article
ISSN
0749-1581

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✦ Synopsis


Abstract

Empirical correlations for the prediction of the chemical shifts of the carbon atoms in aliphatic alcohols are presented. Structural and conformational effects contributing to the ^13^C chemical shifts of γ‐carbons are discussed.


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The effect of O-methylation on chemical
✍ Stephen J. Angyal; Léon Odier 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 361 KB

The 'H-and "C-n.m.r. spectra of seven in&lo1 methyl ethers were recorded and assigned. They were classified into five types, and the effect of 0methyl&ion on the chemical shifts of each type is discussed. NOTE ADDED IN PROOF Type F, not encountered in our work, occurs in 1,6-anhydro-3-O-methyl-& D