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13C-NMR characterization of poly(1,5-hexadiene)

✍ Scribed by H. N. Cheng; N. P. Khasat

Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
192 KB
Volume
35
Category
Article
ISSN
0021-8995

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✦ Synopsis

Synopsis

Poly(l,5-hexadiene) was prepared and its structure characterized by high-field I3C nuclear magnetic resonance. The polymer was shown to contain repeating five-membered rings separated by methylene bridges, with both cis and truns placements present in a 54 : 46 ratio. The result is compatible with the Marvel-Garrison two-step reaction mechanism.

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