There is a vast and often bewildering array of synthetic methods and reagents available to organic chemists today. The *Best Synthetic Methods* series allows any scientist who is interested in the chemical transformations of molecules to choose between all the alternatives and assess their real adva
13C-NMR and CNDO/2 calculations of compounds containing SP-hybridised carbon. Acetylenes and cumulenes.
โ Scribed by J.P.C.M. van Dongen; M.J.A. de Bie; R. Steur
- Book ID
- 104246878
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- French
- Weight
- 211 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0040-4039
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NMR spectra are reported for an acetylenic ketone enriched with 13C in the acetylenic carbon atoms that exhibits extremely strong C-C coupling. Chemical shifts and coupling constants have been extracted from computer simulations of the second-order 'H and I3C spectra. The two acetylenic carbon atoms
## Abstract An unprecedented new natural product named nocarsin A (1), 5__H__โ4a,6,7aโtriazacyclopenta[__cd__]indeneโ5,7(6__H__)โdione (1), together with seven known compounds lumichrome (2), cyclo (LโLeuโLโTyr) (3), cyclo (LโAlaโLโIle) (4), cyclo (LโAlaโLโLeu) (5), cyclo (LโValโLโAla) (6), 5โmethy