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13C CP/MAS and2H NMR study of tert-butyl alcohol dehydration on H-ZSM-5 zeolite. Evidence for the formation of tert-butyl cation and tert-butyl silyl ether intermediates

โœ Scribed by Alexander G. Stepanov; Kirill I. Zamaraev; John M. Thomas


Book ID
112400597
Publisher
Springer US
Year
1992
Tongue
English
Weight
769 KB
Volume
13
Category
Article
ISSN
1011-372X

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## Abstract The molecular mobility and dehydration reaction of __tert__โ€butyl alcohol, selectively deuteriated in the methyl groups (__t__โ€BuOH[2 โ€“ ^2^H~9~], dTBA), absorbed on Hโ€ZSMโ€5 zeolite was studied using ^2^H NMR spectroscopy. At 173โ€“298 K two modes of fast anisotropic motion were observed f