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13C chemical shift sensitivity to charge in delocalized carbocations and its relation to ring current anisotropy

✍ Scribed by Eliasson, Bertil; Johnels, Dan; Sethson, Ingmar; Edlund, Ulf; M�llen, Klaus


Book ID
120255809
Publisher
Royal Society of Chemistry
Year
1990
Tongue
English
Weight
555 KB
Volume
6
Category
Article
ISSN
1472-779X

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13C NMR spectra of para-substituted methoxybenzenes and phenols were recorded in the solid state to gain an insight into the manner and origin of substantial peak splittings in the ortho (up to 9.2 ppm) and mefa (up to 2.5 ppm) carbon signals. It was difficult to account for these peak splittings on