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13C, 13C coupling constants of isotopically perturbed molecular systems: Cyclohexane, benzene

✍ Scribed by Vitaliy A. Roznyatovsky; Nickolay M. Sergeyev; Vyacheslav A. Chertkov

Book ID
102529491
Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
306 KB
Volume
29
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

^13^C, ^13^C coupling constants in benzene and cyclohexane were measured using monodeuteriated derivatives where ^13^C, ^13^C two‐spin subsystems become slightly non‐equivalent (benzene, ^1^J = 55.88, ^2^J = 2.46, ^3^J = 10.04; cyclohexane, ^1^J = 33.10, ^2^J = 2.12, = ^3^J 2.05; all couplings in hertz within the error limits of 0.01 Hz). ^12^C/^13^C isotope effects for the ^13^C chemical shifts were found to be non‐additive.

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