Surface oxygen groups on carbon blacks were analyzed by several new techniques and some methods used previously were re-examined. Phenolic hydroxyl groups were converted to their acetate ester derivatives using radioactively labeled acetic anhydride in pyridine at 90Β°C. The drop in count rate on hyd
139. Surface hydroxyl groups in carbon blacks
β Scribed by P.H. Given; Loren W. Hill
- Publisher
- Elsevier Science
- Year
- 1964
- Tongue
- English
- Weight
- 131 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0008-6223
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Three methods were employed to introduce sulfur groups (thiol and thio ester groups) onto the surface of a carbon black. Positive results were obtained and controled by functional group analysis and radiochemistry.
The chlorination of carbon blacks at the optimum temperature of 450" results in fixation of chlorine and formation of hydrogen chloride, the amount depending to some extent, upon the hydrogen content. A part of the chlorine appears to be fixed by addition at the unsaturated sites and the rest by sub
## AM-Interaction of carbon black and aqueous bromine involve8 conversion of the halogen into hydrobromic Acid a8 well a8 chemkorption or "iixation" by the carbon black. The amount converted varies with surface acidity of the black while the amount fixed varies with the amount of CO,-complex elimi