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137. The kinetics and mechanism of carbonyl–methylene condensation reactions. Part XI. Stereochemistry of the products

✍ Scribed by Zabicky, Jacob


Book ID
121418096
Publisher
The Royal Society of Chemistry
Year
1961
Weight
424 KB
Volume
0
Category
Article
ISSN
0368-1769

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✍ B. Van Mele; C. Tybaert; G. Huybrechts 📂 Article 📅 1987 🏛 John Wiley and Sons 🌐 English ⚖ 312 KB

The kinetics of the Diels-Alder additions of CH,= CHCHO, CH2= C(CHdCH0, and CH2= CHC(CH,)O to cyclohexa-1,3-diene (CHD) have been studied in the gas phase. The stereochemistry and the mechanism of these reactions are discussed. In contrast with other Diels-Alder additions involving CHD as diene, a b