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1,3,5-Tri-tert-Butylpentalene. A Stabilized Planar 8π-Electron System

✍ Scribed by Prof. Dr. Klaus Hafner; Dipl.-Chem. Hans Ulrich Süss


Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
318 KB
Volume
12
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES


Reactions of 1,3,5-Tri-tert-butylcyclope
✍ Dehmlow, Eckehard V. ;Bollmann, Christof 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 332 KB

Title compound 1 is sterically shielded to such an extent that many "normal" reactions cannot occur. It is possible, however, to prepare the carboxylic acid 2, its acyl chloride 3 and the oxidation product 4. Furthermore, halogen substitutions to yield 5 and 6 and trialkylstannations to give 8a, b c