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1,3-Thiazoline-5-thiolates and 1,3-Thiazole-5(2H)-thiones by [3+2]-Cycloaddition of Carbon Disulfide to Metalated 4-Alkylidene-4H-pyridin-1-ides

✍ Scribed by Diana Hampe; Helmar Görls; Ernst Anders


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
292 KB
Volume
2005
Category
Article
ISSN
1434-193X

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A series of 4-(alkylidene/arylidene)amino-5-(2-furanyl)-2.4-dihydro-3H-I .2.4-triazolc-3-1hiones (2) and 6-aryl-3-(2-furanyl)-7H-12.4-triazolo[3,4-b]( 1.3.41 thiadiazines (3) werc synthesized. The configuration of 2g was assigned on che basis of 'H-NMR data. Of the new derivatives tesced. only 2b. 2