✦ LIBER ✦

1,3-Migration of chloride and azide substituents within organosilicon cations, and anchimeric assistance by the azido group

✍ Scribed by Colin Eaborn; Paul D. Lickiss; Sabah T. Najim; M.Novella Romanelli

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 251 KB
Volume: 315
Category: Article
ISSN: 0022-328X
DOI: 10.1016/0022-328x(86)80420-x

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

1,3-Migration of chloride and azide subs

1,3-Migration of chloride and azide substituents within organosilicon cations, and anchimeric assistance by the azido group: J. Organomet. Chem. 315 (1986) C5–C8

📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 70 KB

Reactions of Unsaturated Azides, 6. Synt

Reactions of Unsaturated Azides, 6. Synthesis of 1,2,3-Triazoles from Propargyl Azides by Rearrangement of the Azido Group. – Indication of Short-Lived Allenyl Azides and Triazafulvenes

✍ Banert, Klaus 📂 Article 📅 1989 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 850 KB

## Triazoles, preparation of Treatment of 3-bromo-3-methyl-I-butyne (1) or 1 4odo-3-methyl-13-butadiene (3) with solutions of sodium azide affords 3-azido-3-methyl-1-butyne (5) which reacts already at room temperature to 1,2,3-tn'azoles 8-11. Structures of 5 and 8-11 are verified by independent sy