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[1,3]-Hydrogen sigmatropic rearrangements in alkyl-substituted allenes

โœ Scribed by Pasto, Daniel J.; Brophy, John E.


Book ID
126424107
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
417 KB
Volume
56
Category
Article
ISSN
0022-3263

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1,3-hydrogen shift in phosphapropenes. S
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Ab initio molecular orbital calculations at the QCISD(T)/&311+ +G(d,P)//MP2/6-31G(d,p)+ZPE level show that the suprafacisl 1,3-hydrogen shifts in the I-phosphapropene-vinylphosphine ( H&-CH=PH=H,C=CH-PH2) and degenerate 1,3diphosphapropene (H\*P-CH-PH=HP=CH-PH,) rearrangements do not only exist but