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1,3-Dipolar cycloadditions to alkyldicyanamides

✍ Scribed by P. H. Benders; D. N. Reinhoudt; D. M. W. van den Ham


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
413 KB
Volume
100
Category
Article
ISSN
0165-0513

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✦ Synopsis


Abstract

The 1,3‐dipoles 2,4,6‐trimethylbenzonitrile oxide and benzyl azide react with alkyldicyanamides (1) to give the 3,5‐disubstituted 1,2,4‐oxadiazoles 2 and the 1,5‐disubstituted tetrazole 4, respectively, by (3 + 2)‐cycloaddition. The structure of 4 has been determined by a single crystal X‐ray analysis.


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