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1,3-Dipolar cycloadditions of nitrones to α,β-unsaturated γ-lactams derived from (S)-pyroglutaminol

✍ Scribed by Nicole Langlois; Nguyen Van Bac; Nathalie Dahuron; Jean-Marc Delcroix; Abdallah Deyine; Dominique Griffart-Brunet; Angèle Chiaroni; Claude Riche

Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
946 KB
Volume
51
Category
Article
ISSN
0040-4020

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1,3-Dipolar cycloadditions of cyclic nit
1,3-Dipolar cycloadditions of cyclic nitrones to γ-bromo α,β-unsaturated esters and lactones
✍ Pedro de March; Marta Figueredo; Josep Font; Antonio Salgado 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 630 KB

The 1,3-dipolar cycloaddition of cyclic nitrones to several "t-bromo ct,~unsaturated esters and lactones has been studied. All the reactions have shown high stereoselectivity, with a predominance of the endo or exo transition state for the trans or cis dipolarophiles, respectively.