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1,3-Dipolar Cycloadditions of Benzonitrile Oxide with Various Dipolarophiles in Aqueous Solutions. A Kinetic Study

✍ Scribed by van Mersbergen, Dick; Wijnen, Jan W.; Engberts, Jan B. F. N.


Book ID
115468532
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
66 KB
Volume
63
Category
Article
ISSN
0022-3263

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Second-order rate constants and activation parameters of 1,3-dipolar cycloaddition reaction between C,N-diphenylnitrone and dimethyl fumarate were obtained in various solvents and aqueous solutions at 65ЊC. Second-order rate constants of the reaction in water and ethylene glycol are approximately 33