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1,3-Dipolar cycloaddition reactions of benzo[h]naphthyridinium N-phenacylides

✍ Scribed by Barbara Bachowska; Wanda Śliwa

Publisher: Springer Vienna
Year: 1984
Tongue: English
Weight: 308 KB
Volume: 115
Category: Article
ISSN: 0026-9247
DOI: 10.1007/bf00798776

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## Abstract The thermal reactions of the 2,2,3‐trisubstituted __N__‐phthalimidoaziridine **1a** with dimethyl acetylenedicarboxylate (DMAD), thioketones **4a**–**4d**, and dimethyl azodicarboxylate (**5**) proceed even at room temperature leading to the five‐membered cycloadducts **2a, 6**–**8**, a