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1,3-Dipolar cycloaddition or nucleophilic addition: Influence of solvents and nature of substituents in the reagent and substrate molecules on the reaction of 4,5-dihydro-1H-imidazole 3-oxides with alkynes

โœ Scribed by Sergey A. Popov; Vladimir A. Reznikov


Publisher
Journal of Heterocyclic Chemistry
Year
2006
Tongue
English
Weight
191 KB
Volume
43
Category
Article
ISSN
0022-152X

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โœฆ Synopsis


Two competitive processes -1,3-dipolar cycloaddition and nucleophilic addition -in the reaction of 4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole 3-oxides with asymmetrically substituted alkynes were shown to occur. The influence of solvents and the nature of substituents in the reagent and substrate molecules on the rate ratio of these competitive processes were studied.


๐Ÿ“œ SIMILAR VOLUMES


1,3-Dipolar Cycloaddition or Nucleophili
โœ Sergey A. Popov; Vladimir A. Reznikov ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› John Wiley and Sons โš– 22 KB ๐Ÿ‘ 1 views

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