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1,3-Dipolar cycloaddition ofin situgenerated 2,2-dimethyl-and 2,2-dichlorodiazocyclopropanes to 3,3-dimethylcyclopropene

✍ Scribed by Yu. V. Tomilov; E. V. Shulishov; I. P. Klimenko; O. M. Nefedov

Book ID
112537325
Publisher
Springer
Year
1996
Tongue
English
Weight
500 KB
Volume
45
Category
Article
ISSN
1573-9171

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1,3-Dipolar cycloadditions of 9-diazoflu
1,3-Dipolar cycloadditions of 9-diazofluorenes and diphenyldiazomethane to 2-acyl-2H-1,2,3-diazaphospholes
✍ Xiangyun Guo; Li Feng; Quanrui Wang; Zhiming Li; Fenggang Tao πŸ“‚ Article πŸ“… 2006 πŸ› Journal of Heterocyclic Chemistry 🌐 English βš– 483 KB

2H-1,2,3-diazaphospholes 3 underwent ready 1,3-dipolar cycloaddition reactions with 9-diazofluorenes as the 1,3-dipole, yielding the respective bicyclic phosphiranes 5 or trimers 7 depending on the reaction conditions employed. The reaction is believed to proceed via the formation of the [3+2]cycloa