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1,3-Dipolar Cycloaddition of Azomethine Ylides to Aldehydes: Synthesis of anti α-Amino-β-Hydroxy Esters

✍ Scribed by Jakob Danielsson; Lauri Toom; Peter Somfai

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
273 KB
Volume
2011
Category
Article
ISSN
1434-193X

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## Amino alcohols Q 0240 1,3-Dipolar Cycloadditions of Carbonyl Ylides to Aldimines: A Three-Component Approach to syn-α-Hydroxy-β-amino Esters. -Addition of ethyl diazoacetate to a benzylidenebenzylamine under the conditions shown results in formation of syn-α-hydroxy-β-amino esters with high dia

1,3-Dipolar Cycloadditions of Carbonyl Y
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The b-amino alcohol and a-hydroxy-b-amino acid moieties are found in a large variety of biologically important compounds and natural products [1] as well as in a growing number of ligands and chiral auxiliaries for asymmetric synthesis. [2] Existing synthetic routes towards enantiopure vicamino alco