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1,3-Dipolar Addition of Azomethine-imines onto Alkylidene-imines, Nitriles, and Thiocyanates

✍ Scribed by Dr. R. Grashey; H. Leitermann; R. Schmidt; cand.chem. K. Adelsberger


Publisher
John Wiley and Sons
Year
1962
Tongue
English
Weight
193 KB
Volume
1
Category
Article
ISSN
0044-8249

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With longer-chain carbonamides, partial isomerization occurs. For example, crotonamide yields 68 % a-methylsuccinimide and 19 % glutarimide. Alicyclic unsaturated carbonamides form bicyclic imides. 0 II Cyclohexenecarbonamide forms hexahydrophthalimide in 91 % yield.