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1,3-Dimethylimidazolidiniodithioacetates; stable inner salts having a 1,4-dipolar structure

✍ Scribed by Juzo Nakayama; Keiichi Akimoto; Yoshiaki Sugihara

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
254 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

Addition of carbon disulfide to 2-isopropylidene-and2-methylene-l,3dimethylimidazolidines gave the thermally stable, crystalline inner salts, 1,3-dimethylimidazolidiniodithioacetates (10 and 12), where carbenium ion and dithiocarboxylate parts are insulated by an sp 3 carbon atom. X-Ray diffraction analyses of these compounds and the reaction of 10 with DMAD are described.

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