1,3-Cyclohexadiene polymers. Part I. Preparation and aromatization of poly-1,3-cyclohexadiene
✍ Scribed by Lefebvre, G. ;Dawans, F.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1964
- Tongue
- English
- Weight
- 1009 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0449-2951
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## Abstract Star‐shaped, star‐__block__‐linear, and hyperbranched poly(1,3‐cyclohexadiene) (PCHD) (co)polymers were synthesized through a convergent living anionic polymerization process or via addition of divinylbenzene. Chemical modification of star‐shaped PCHDs, including aromatization, hydrogen
## Abstract **Summary:** The reactivity of poly(1,3‐cyclohexadienyl)lithium (PCHDLi), as a species for the propagation of the anionic polymerization of 1,3‐cyclohexadiene (1,3‐CHD), was examined using a post‐polymerization reaction of PCHDLi and 9‐bromofluorene (9‐BFL). The degree of nucleophilicit