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1,3-Butadiene Polymerization by Bis(benzimidazolyl)amine Metal Complexes: Remarkable Microstructural Control and a Protocol for In-Reactor Blending of trans -1,4-, cis -1,4-, and cis -1,4- co -1,2-Vinylpolybutadiene

✍ Scribed by Cariou, Renan; Chirinos, Juan; Gibson, Vernon C.; Jacobsen, Grant; Tomov, Atanas K.; Elsegood, Mark R. J.

Book ID: 125974297
Publisher: American Chemical Society
Year: 2009
Tongue: English
Weight: 151 KB
Volume: 42
Category: Article
ISSN: 0024-9297
DOI: 10.1021/ma802633q

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✍ Dirong Gong; Baolin Wang; Chenxi Bai; Jifu Bi; Feng Wang; Weimin Dong; Xuequan Z 📂 Article 📅 2009 🏛 Elsevier Science 🌐 English ⚖ 228 KB

Fe(III), Cr(III), Fe(II), Co(II) and Ni(II) chloride complexes supported by 2,6-bis [1-(iminophenyl)ethyl]pyridine have been synthesized and characterized along with single crystal X-ray diffraction. These complexes, in combination with MAO, have been examined in butadiene polymerization. The cataly