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1,3-Anionic Cycloaddition of 2-Azaallyllithium Compounds to Nitriles

✍ Scribed by Prof. Dr. Thomas Kauffmann; Dipl.-Chem. Alfred Busch; Dipl.-Chem. Kai Habersaat; Dr. Edgar Käppelmonn


Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
208 KB
Volume
12
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES


Anionic 3 + 2 Cycloaddition of a 1,2-Dia
✍ Prof. Dr. Thomas Kauffmann; Dr. Dieter Berger; Björn Scheerer; Annegret Wolterma 📂 Article 📅 1970 🏛 John Wiley and Sons 🌐 English ⚖ 195 KB

The energy barrier to be overcome in anionic 3 + 2 cycloadditions according to (A) (21 and the corresponding cyclo--~~~' 1 ~~H 5 eliminations according to (8) (X = 0, S)[31 should be low since the symmetry of the ~i orbitals is conserved [4+51. The direction of reaction is dictated by the arrangemen