1,2β-Dimethoxycarbonyl-3aα-hydroxy-2a,3,3,8,8aα-pentahydropyrrolo[2,3-b]indole
✍ Scribed by Flippen, J. L.
- Book ID
- 114524977
- Publisher
- International Union of Crystallography
- Year
- 1978
- Weight
- 257 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0567-7408
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## Abstract A synthesis of (2__R__,3a__R__,8a__R__)‐6‐chloro‐3a‐hydroxy‐1,2,3a8,8a‐hexahydropyrrolo[2,3‐__b__]indole‐2‐carboxylic acid methyl ester (1) was achieved. An aldol reaction with Garner aldehyde, a hydroxyl introduction by Davis reagent, and a reductive intramolecular ring‐closure reactio
1998 structure structure (organic substances) K 9000 29 -034 [3aR-(3aα,4α,7α,7aα)] -2-Acetyl-4,8,8-trimethylperhydro-4,7methano-1,2-benzisoselenazol-3a-ol . -The absolute configuration of title compound (I) is determined by X-ray crystallography. The five-membered heterocyclic ring has envelope con