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12C16O2in Emission in the 4.5-μm Region: Transitionsv1vl2v3→v1vl2(v3−1) with (2v1+v2) = 6 Occurring between Highly Excited Vibrational States

✍ Scribed by D. Bailly

Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
226 KB
Volume
192
Category
Article
ISSN
0022-2852

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✦ Synopsis

Eight emission spectra of CO 2 ϩ N 2 mixtures excited by dc discharge were recorded using a Fourier Transform Spectrometer (Bruker Spectrometer 120HR) with a resolution of 0.003 cm Ϫ1 in the 4.5-m region. Results (wavenumbers, band centers, spectroscopic constants) concerning 13 new vibrational transitions which have not been observed earlier and which occur between highly excited levels (hence their very small population) are reported. The derived spectroscopic parameters allow the reproduction of the experimental wavenumbers with a RMS Ͻ 3 ϫ 10 Ϫ4 cm Ϫ1 .

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